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Wednesday, September 25, 2024

The Devolution Of Hydrogen For Vitality Over 25 Years Is A Fascinating Story


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About 25 years in the past, hydrogen was the answer of selection for climate-aware technocrats and politicians, and with good cause. On the time, there actually wasn’t a lot selection by way of low-carbon power carriers. Batteries had been ok for laptops and telephones, however clearly nobody was going to be operating transportation, heating or grid storage with them.

And apart from, you could possibly make hydrogen with electrical energy, one thing first executed in 1800, and a staple of children’ science courses as early as grade 4. Straightforward to make, excessive power density and also you didn’t even need to burn the stuff. You may use gas cells, and once more, these had been actually previous expertise with the primary one constructed in 1842, and gas cells utilized in Gemini spacecraft way back to 1962. What’s to not love?

The temper was greatest captured by American economist and social theorist Jeremy Rifkin in his guide The Hydrogen Economic system: The Creation of the Worldwide Vitality Net and the Redistribution of Energy on Earth. What’s that? You didn’t keep in mind the remainder of the title? Nobody does.

It’s value declaring that Rifkin, whereas undoubtedly good and a fantastic thinker, has no engineering or science chops to talk of. He by no means did rigorous price workups on hydrogen electrolysis services, renewable energy and the grid costings or labored via the implications of distribution of hydrogen in any depth. He was seduced by the molecule, and was deeply influential in each Europe and America concerning it, for instance getting the then President of the European Fee to decide to a multi-billion Euro analysis and improvement plan to show Europe right into a inexperienced hydrogen superpower.

Is he nonetheless as bullish on hydrogen as he was in 2002 when the guide was revealed? Not a lot. Feedback within the final yr have seen him retrenching to a place the place solely long-haul logistics see any want for hydrogen gas cell autos. He hasn’t fairly acquired the complete memo but.

At the same time as early as 2005 it was apparent that there have been severe issues with this imaginative and prescient. Iceland ran three hydrogen buses for 4 years, funded by EU cash after all to the tune of €12 million in 2023 cash. Did they hold the buses on the highway when the cash ran out? Not an opportunity. Far too costly, far too failure susceptible.

Has something modified with hydrogen buses since then? Sure, there have been hydrogen bus trials on a number of continents which recreated the Icelandic expertise. A number of governmental cash, very excessive prices to gas, very excessive upkeep prices, abandonment when funding is withdrawn.

Lately I stepped via California’s newer six years of experiences, discovering that after a number of years of operation, their gas cell buses price 50% extra per yr to keep up than their diesel buses, and about twice as a lot as their battery electrical buses. Additional, California’s hydrogen refueling stations within the final six month for which knowledge was collected, the primary half of 2021 after years of operation when lemons ought to have been eradicated and upkeep optimized, had been out of service 20% extra hours than they had been really pumping hydrogen and had been costing 30% of capital expenditures per yr in upkeep, an order of magnitude above assumed prices.

In the meantime, electrical buses have taken over the world. China has approaching 700,000 on their roads, in comparison with a few thousand gas cell buses, principally in Foshan, a metropolis which made an industrial and export coverage option to concentrate on hydrogen for transportation. Even Foshan has extra battery electrical buses than gas cell ones nonetheless. Europe is shopping for 1000’s of battery electrical buses yearly, a couple of third with at the least Chinese language frames, drive trains, motors and batteries and sometimes your entire bus being delivered from the opposite aspect of the world. African nations are shopping for 1000’s of electrical buses, not hydrogen gas cell buses. India has 1000’s on its roads already and is aiming for 50,000 by 2027.

That hasn’t stopped transit companies, funded by governmental cash at numerous ranges, from stepping into bother by shopping for hydrogen buses. The newest seems to be Spain, the place the 5 Mallorcan buses have been sitting unused and unusable as a result of refrigerant leaked in and destroyed the gas cells — one in every of many issues with hydrogen autos is that gas cells demand pure hydrogen and fairly pure air and are deeply illiberal of the rest — and solely 4 of eight Barcelona buses are operational, 18 months or so after they arrived. Regardless of these failures and the success of their battery electrical buses, Barcelona is ordering extra hydrogen lemons with EU funding.

Within the 2000s, Method Scholar, a worldwide initiative the place mechanical engineering college students at totally different faculties construct small automobiles and compete on about fifteen totally different standards together with acceleration, dealing with, financial viability and the like, had a brand new class for zero emission autos. For the last decade, a bunch of colleges selected hydrogen and a bunch selected batteries. On the finish of the last decade, battery electrical automobiles had been threatening the traditional inside combustion engines. Early within the 2010s, one gained total. Final yr, a battery electrical entrant accelerated from zero to 100 km/h in 0.956 seconds inside a distance of 12.3 meters. As of final yr, there was precisely one hydrogen entrant left, and it probably gained’t final.

In 2003, a few issues are worthy of notice. Amory Lovins, who did wonderful work and based the RMI, thought hydrogen was the reply, together with for his Hypercar, one in every of his few failures of study, because the Hypercar was a hyperefficient hairshirt in vehicular type. In the meantime, on the opposite aspect of the Rockies, Tesla was based with the premise that they had been going to construct absolutely electrical automobiles that drivers would salivate over.

The unique Roadster run of two,500 was offered out as quickly as they may get them off the manufacturing facility flooring, most pre-sold in truth. The Tesla Mannequin S’ arrival in 2012 was the demise knell for the inner combustion automotive. Toyota clearly didn’t perceive this, introducing the hydrogen-powered Mirai in 2014. Over half of the 23,000 delivered had been offered within the USA, particularly in California the place there have been the often-not-working hydrogen refueling stations talked about earlier. The gross sales of hydrogen from these stations make it clear that California’s hydrogen autos journey a mean of 15 miles per day, properly underneath the 37 miles per day that Individuals sometimes drive.

Now we’re at some extent the place each legacy producer and a bunch of latest ones, particularly from China but additionally Vietnam, have a number of electrical automobiles of their lineups and solely a pair nonetheless maintain onto the clean-burning torch for hydrogen. Some, like Toyota, are leaning into hybrids, however most are going absolutely electrical. It’s onerous to discover a severe analyst who thinks that there’s a spot for hydrogen in gentle autos, though corporations like Ballard and Plug Energy proceed to faux in any other case.

One of many nice hopes of fuel utilities is that they might be pumping hydrogen via their pipelines into properties and buildings for heating and cooking within the coming a long time. They wish to begin by mixing hydrogen into pipelines with pure fuel in what must be homeopathic quantities for a couple of apparent technical causes. They’ve invested some huge cash into attempting to persuade politicians that it is a affordable thought, when it actually isn’t.

Many hydrogen lovers had been trying ahead to proceed to cook dinner with fuel, albeit with a paler blue flame. They weren’t considering via the implications of getting a fuel inside their properties that’s way more flammable over a much wider vary of concentrations that may ignite with decrease temperature sparks and that couldn’t have odorants added to it. Security research make it clear it’s 4 occasions extra prone to trigger explosions and hurt than pure fuel, one thing that destroys about 4,000 buildings a yr within the USA at current.

Even hydrogen-focused Japan realized that this was silly, therefore the explanation that a number of the greatest warmth pump corporations on the earth are Japanese, Mitsubishi and Daikin amongst them. Touring round many components of the world that aren’t Europe or North America, you’re more likely to seek out induction range tops than the rest.

Whereas low-carbon hydrogen would both require throwing away half of the power in pure fuel at nice expense, tripling or extra the price of warmth, or having inexperienced hydrogen made out of low-carbon electrical energy at even better expense, warmth pumps get three items of warmth from the atmosphere for one unit of electrical energy. On common, they’re 4 occasions extra environment friendly than pure fuel furnaces, decreasing heating payments in lots of locations and offering air-con as properly. And induction range tops warmth up solely the pot or pan, offering the moment warmth of fuel stoves with not one of the dangers and extra effectivity than older electrical range tops.

There at the moment are 54 impartial research which make it clear that hydrogen has no place in properties or industrial buildings. And if it has no place in buildings, there’s no future for fuel utilities and there might be no handy and cheap hydrogen community used for a large number of functions operating via cities. Goals of utilizing that non-existent community to deliver hydrogen to truck stops are simply that, desires. District heating and cooling programs that more and more use large floor or water supply warmth pumps are a a lot larger development phase.

There’s a powerful pattern rising, isn’t there. That widespread hydrogen for power economic system is getting narrower and extra constrained with every passing yr.

We’re now at some extent the place there are just a few locations the place hope is being held out for hydrogen. Whereas buses are an answered query the place hydrogen is barely being stored alive by long-running governmental bureaucracies created to dole out cash for hydrogen transportation, many think about freight trucking to be an apparent match. It’s not practically so apparent when you begin trying on the knowledge extra clearly.

There at the moment are a number of heavy truck producers delivering battery electrical semi tractors, together with Tesla. And, after all, Tesla’s performs far above the remainder of them for a cheaper price level, leveraging the large economies of scale for batteries, electrical motors, energy administration programs and high-powered quick charging its dominance in gentle electrical autos supplies. It additionally averted the entice different producers fell into attempting to economize by reusing present semi ladder frames as a substitute of constructing the automobile from the bottom as much as be electrical.

That’s why in September 2023’s NACFE Run on Much less, the Tesla vehicles had been capable of put in full days of labor masking over 1,000 miles (1,600 km) with a few recharging breaks. Tesla is making the megawatt scale charging customary for its Supercharger community, and keep in mind that in North America, Tesla’s plug is now the usual. Legacy truck producers have a selection. They will both comply with Tesla down the pure electrical highway, or proceed to faff about with batteries, hydrogen or diesel within the body optimized just for the latter power provider. In the event that they persist, their vehicles might be dearer and fewer succesful than not solely Tesla’s, but additionally Chinese language autos.

Current whole price of possession research together with the fatally flawed Worldwide Council on Clear Transportation’s November 2023 effort put each thumb on the dimensions doable for hydrogen trucking and nonetheless discovered that in each single class of trucking from lightest to heaviest, battery electrical vehicles have one of the best TCO, decrease than diesel and decrease than hydrogen even leaving the thumbs intact. These research have additionally been utilizing 3% and 4% of capital expenditure for refueling stations because the annual price of upkeep, primarily based on guesses from the mid-2010s that turned enshrined in report after report as a result of nobody bothered to take a look at the actual upkeep knowledge that was accessible from Europe and California. As famous, 30% is California’s expertise, including over US$9 per kilogram distributed by itself.

Organizations not realizing that battery electrical has already gained faux vehicles can’t drive far sufficient or that batteries are too heavy. The ICCT once more thinks batteries gained’t obtain 500 watt hour per kilogram power densities, double Tesla’s, till 2050. In the meantime, the world’s greatest battery producer, CATL, launched a 500 Wh/kg battery in 2023. That allows a Tesla Semi to to journey 750 miles between recharges whereas weighing rather a lot much less, or journey 1,000 miles with the identical fully affordable 2% to three% further weight allowance. And silicon chemistries already commercializing promise double to quintuple CATL’s power density and therefore longer ranges, decrease weights or each.

I’m engaged in a overview group of a complete price of possession examine for European freight trucking now, the explanation I went and checked out California’s bus and refueling station upkeep. One in all my feedback was that sure mixes of autos, resembling hydrogen and light-weight autos, needs to be excluded as that debate is over, however that hydrogen for vehicles needs to be stored in as a result of some individuals refuse to just accept the truth and so driving it house with one other examine continues to be helpful.

Global perspective on rail electrification vs rail network length by Michael Barnard, Chief Strategist, TFIE Strategy Inc
International perspective on rail electrification vs rail community size by Michael Barnard, Chief Strategist, TFIE Technique Inc

After which there’s heavy rail. That query has been answered as properly. Exterior of North America, the world is solely getting on with electrifying the components of the rail community that don’t have already got overhead wires. India expects to be 100% electrified in 2024, main the world. All of China’s large and rising community of high-speed rail is inspired, as are the high-speed rail programs in Indonesia and Morocco. China is delivering freight to Europe alongside absolutely electrified rail.

And whole price of possession research are clear right here too. Baden-Würtemberg did it proper. They put a gimlet-eyed spreadsheet jockey on the job, advised them to check grid-tied, battery electrical and hydrogen rail programs, and hybrids of them. The reply got here again that the place they couldn’t put in overhead wires as a result of it was too costly, principally bridges and tunnels constructed with out overhead wires and the strains which have lots of them, batteries had been nearly as low cost as overhead wires, whereas hydrogen was thrice as costly. In the meantime, subsequent door in Decrease Saxony, they took a few of that pretty governmental cash, about €14 million per prepare, to purchase some hydrogen trains and a yr after beginning service with them introduced they might not purchase any hydrogen trains ever once more.

The USA will get to electrifying rail too, and drag Mexico and Canada together with it into the twenty first Century of rail, however not till it’s wasted as a lot time as doable scraping out what Wall Avenue analysts wish to hear each three months.

Hmmm… no floor transportation demand for hydrogen. In any respect. And with renewables offering the entire power, not a lot room in any respect for hydrogen within the electrical energy system. Whereas it’s not on the infographic, as room didn’t allow, let’s speak about that. The entire coal, pure fuel and oil burned for electrical energy right now should go away if we’re to unravel local weather change. The concept of carbon seize on energy technology vegetation has been tried, and it’s vastly dearer and fewer efficient than any rational actors are keen to contemplate.

We’re now into the top sport of 1 / 4 century of sadly misguided power coverage, kicked off largely by Rifkin’s guide and proselytizing in Europe and North America.

However wait, the hydrogen advocates say. We’ll want hydrogen for electrical energy storage! Nicely, no. That’s really a solved downside apart from continent-scale, weeks-long lulls in sunshine and wind which solely come alongside each few a long time. Even within the archipelago nation of the UK, modeling solely finds that may be a important downside each decade or so.

For fast-response, short-duration storage, the sort that’s nice for peaks and smoothing spiky energy, in addition to transferring solar energy a small handful of hours into the long run, the identical more and more low cost batteries in an growing number of chemistries are fully sufficient. For longer length storage, the identical pumped hydro that was constructed to offer nuclear vegetation one thing to do at evening and that represents 93% of grid power storage right now covers from 4 hours to 24 hours of storage fairly simply.

Australian National University global map of pumped hydro resources
Australian Nationwide College world map of pumped hydro sources

China will get this. It’s constructed 58 GW of pumped hydro already, with most likely 600 GWh to greater than a TWh of power capability. It’s constructing or has in plan one other 365 GW of capability representing 4 to eight TWh of power storage by 2030. The remainder of the world has woken as much as this previous resolution as properly. The Australia Nationwide College’s greenfield off-river, closed-loop pumped hydro atlas is undoubtedly getting an enormous work out. They did the examine a couple of years in the past of all areas the place small space higher and decrease reservoirs may very well be positioned moderately shut collectively, avoiding streams and rivers, with over 400 meters of head peak to offer a lot of power, close to transmission and off of protected lands. A bunch of the clean areas within the map like Siberia simply didn’t have any good knowledge, however undoubtedly have a lot of sources.

The ANU estimates that there are 100 occasions the power storage sources accessible for the top state of full electrification in these recognized websites, and 200 occasions in North America. And with HVDC transmission, storage doesn’t need to be proper beside both the technology or the demand heart. Hong Kong’s pumped hydro backup system of 25 GWh is a few hundred kilometers away in mainland China, for example.

Then there may be the rising expertise of redox move batteries, the place you possibly can scale up massive tanks of chemical compounds on both aspect of the two-way fuel-cell equal expertise within the center and retailer lots of power. There are a handful of commercialized options already and extra in improvement.

It’s actually solely that 10 to 50 years dunkeflaute the place inefficient, onerous to retailer, onerous to make use of hydrogen nonetheless has any alternative to play, and even there, if the query is “What molecule ought to we retailer as a strategic power reserve?” it’s onerous to not discover higher alternate options like capturing a bunch of the methane emitted from human biomass waste in landfills and the like and put it into present pure fuel strategic reserves. You actually have to begin with discovering a use case for hydrogen, as Sir Chris Llewellyn’s UK examine that threw out pumped hydro with out consideration and downplayed HVDC interconnect potential did, after which announce that inexperienced hydrogen was the reply there, so by definition it might be a solution for shorter length storage too.

So there’s little or no for hydrogen to do for power on land, the place the overwhelming majority of power is consumed. We’re down into the actually quick strokes now, with solely industrial warmth, maritime delivery and aviation left as potential markets.

However 45% of commercial warmth is underneath 200° Celsius and warmth pumps can do this now. There are an terrible lot of organizations that ought to know higher claiming that temperatures above 200° require one thing to burn, however this simply isn’t the case. Resistance heating as much as 600° is already commercialized. 70% of US metal comes from scrap fed via electrical arc furnaces that may generate 1,500° to three,000° warmth. There are microwave, infrared and plasma options. There are a comparatively tiny handful variety of industrial heating necessities that want the traits of an open flame, and as soon as once more, that organic methane which is an enormous local weather downside proper now’s a extra affordable selection than onerous to make, onerous to retailer, onerous to distribute and costly to make use of hydrogen.

However certainly ships want gas, proper? Not as a lot as you’d suppose. There are two 700 unit container ships operating 1,000 kilometer (600 mile) routes on the Yangtze proper now. There’s a 1,000 passenger cruise ship doing three hour excursions within the Three Gorges. There are innumerable battery electrical ferries, utility craft and tug boats already quietly churning via inland and port waters. All inland delivery and about two-thirds of quick sea delivery like routes between Germany and Norway are fully viable with batteries and the place one thing might be electrified, will probably be, just because the operational and upkeep prices are so low that they blow the remainder of the entire price of possession components out of the water.

However that also leaves the massive ships that cross the ocean. Certainly hydrogen has a play there? Nicely, first the excellent news. About 55% of bulk delivery goes to decrease radically. Most of that’s bulk coal, oil and fuel, and that’s going away in any rational world. The remaining is uncooked iron ore, which utilizing inexperienced electrical energy and hydrogen as method to take away extra oxygen — derusting it — from the iron as a substitute of coal will enable way more of it to be processed near mines. Container delivery will go up, however not practically as a lot as bulks go down.

Between shorter haul electrification and dropping lengthy  haul delivery, there’s not practically as a lot power required. My estimate is that about 70 million tons of diesel or equal might be required in 2100. And proper now we already manufacture 70 million tons of biodiesel, we simply waste most of it on floor transportation that might be electrifying.

That is, nonetheless, clearly a case the place the maritime trade and the hydrogen for power varieties haven’t found out the inevitable. Organizations just like the ICCT are nonetheless doing hydrogen for delivery research, together with liquid hydrogen, one thing so tough to work with that the rocket trade is transferring away from it to liquid methane. And the maritime trade has been seduced by ammonia and methanol lobbyists with claims that their present merchandise are as low cost as present maritime fuels — they aren’t  —, that they’re clear burning — that a lot is true —, that they’re low-carbon — that ignores the very excessive upstream carbon debt of creating them — and that truly low-carbon well-to-wake variations might be low cost sooner or later — an entire and utter shameless lie.

In consequence, massive delivery issues like A.P. Moller-Maersk are losing cash on twin gas ships that may run on methanol or ammonia, and LNG ships are a fairly short-sighted development trade. And Maersk is usually contracting for biomethanol, not artificial methanol, in order that’s really dangerous information for hydrogen advocates, not excellent news.The economics will play out as they play out. The Worldwide Vitality Company (IEA) chimed in with a relatively gorgeous report in late 2023 on e-fuels. Even with their very optimistic electrical energy prices from fully new wind and photo voltaic farms dedicated to model new built-in industrial services that generated carbon dioxide in a single course of that was used with inexperienced hydrogen in one other, inexperienced fuels had been 4-6 occasions the price of present maritime fuels and twice as costly as biofuels.

I’ve executed backside up price workups with the at the moment least expensive electrolyzers, customary steadiness of plant figures, and the most affordable, most accessible electrical energy on the planet, Quebec’s US$49 per MWh, 24/7/365, amortized hydroelectric and transmission, and are available at artificial fuels in the identical vary because the IEA.

However electrolyzers are going to get cheaper, shout pissed off hydrogen proponents. It doesn’t matter. They’re maybe 8% of the fee case, so even in case you make them free, artificial fuels gained’t get considerably cheaper. However electrical energy might be free, shout proponents. No, it nonetheless requires transmission, distribution and firming, and the organizations that make it have to make earnings. There might be cheaper electrical energy accessible a portion of the time, however when capital prices are so excessive for e-fuels vegetation, they should be operated at a lot larger capability elements.

So, no hydrogen for delivery. However certainly within the skies? Keep in mind that the area trade that’s a part of aerospace is attempting to maneuver away from liquid hydrogen as a result of it’s so onerous to cope with. Occasional rockets surrounded by extremely educated specialists just isn’t a replicable resolution for industrial aviation. Pure hydrogen in gaseous type can’t get sufficient power on board plane. In liquid type it requires bulbous tanks contained in the fuselage with passengers preferring temperatures about 273° hotter, and that’s in Celsius. These bulbous tanks need to be in the back of the air craft for security of passengers and crew, in order they empty, the airplane would change into nostril heavy and fall out of the sky. There isn’t a path to the certification for hydrogen aviation. Different plane designs gained’t match into any present airports. And airports would have extraordinary prices and challenges coping with liquid hydrogen.

However the aviation trade too has not obtained and understood the memo on hydrogen and derivatives made out of hydrogen. As a reminder, the IEA discovered that artificial fuels can be much more costly than present fuels. However that was in one of the best case state of affairs. The present actuality is that the 25 European artificial sustainable aviation gas proposals haven’t been capable of finding any airways keen to pay the present 10 occasions price of e-kerosene. In consequence, these proposals haven’t reached closing funding choice, one thing that they share in frequent with nearly all inexperienced hydrogen proposals that aren’t for ammonia for fertilizers, a transparent and urgent requirement for decarbonization.

So what is going to plane run on? Unsurprisingly, the airline trade is already shopping for tens of millions of tons of sustainable aviation biofuels and capability is growing often. As soon as once more, whereas 2 to 2.5 occasions dearer than historic prices for fossil kerosene, they’re half one of the best case prices for artificial fuels, and 1 / 4 of the present prices in proposals which were rigorously costed out.

And as soon as once more, batteries are vastly more healthy for function than the trade seems keen to confess and even notice, particularly with hybrid fashions the place divert and reserve power might be within the type of biofuels with an onboard generator. In 2023, a hybrid plane flew for twelve hours earlier than touchdown, and had divert and reserve left over. Coronary heart Aerospace has a whole lot of orders for its 30 passenger hybrid turboprop with 400 kilometers of usable vary. Research in 2023 began displaying the truth that as much as 100 passenger turboprops may have ranges of a thousand kilometers with present battery applied sciences.

The potential exists for ranges of three,000 kilometers with divert and reserve offered by biofuels with silicon chemistries. Even when these chemistries solely double or triple CATL’s 500 Wh/kg, huge quantities of within-continent aviation can run 99% of the time on electrons. Aviation might be slower on this mannequin, however vastly quieter, cheaper and extra environment friendly, so it should find yourself profitable economically, simply as with each different mode of transportation.

In my projection of aviation via 2100, with way more reasonable, decrease projections of aviation development, solely 110 million tons of biofuels might be required in 2100.

And to be clear, biofuels might be made out of waste biomass. Each ton of dried biomass could make about 0.4 tons of biofuels. Do we’ve sufficient waste biomass? We actually do, 2.5 billion tons of meals waste alone globally, and 1.5 billion tons of livestock dung in simply Europe. The primary alcohol to jet gas plant simply opened in Georgia within the USA, one with a goal capability of 9 million tons a yr. That alcohol is made out of biomass that’s fermented and distilled from just about any biomass, however sourced principally from midwestern corn at current. That an alcohol to jet gas plant made closing funding choice and no hydrogen to jet gas plant can obtain that milestone needs to be a key indicator of which means the trade will go.

And so, the top of the hydrogen for power highway. It’s already misplaced gentle autos, with solely relative fanatics pretending in any other case. Buses are a foregone conclusion. The tiny variety of forklifts, 50,000 in whole, are dwarfed by battery electrical gross sales exceeding 1,000,000 a yr. Trucking whole price of possession research and checks like Run on Much less make it clear that there might be no trucking hydrogen, however some individuals haven’t obtained the memo but. Grid storage is a useless finish for the molecule. And even within the two final and diminishing markets for burnable fuels, aviation and delivery, hydrogen has no actual hope of being a part of the answer.

Will the hydrogen for power story finish in 2024? No, after all not. 25 years of bureaucracies and reputations and funding have inertia that may hold it going gone the time when it’s apparent that your entire thought is fatally flawed in each phase it’s thought of in comparison with alternate options that already work higher, are cheaper right now and can stay cheaper.


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